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Biom J 50 , 346363, (2008)

A specific mechanism by which glutathione thiol and glutathione disulfide operate to this aim is the reversible thiol(ate)-exchange mechanism, through which an excess of glutathione thiol regulates in an inhibitory sense the biological pathways which produce reducing cofactors or conditions by binding to sensing, conformation-determining disulfide bonds of proteins in a process termed reversible protein glutathionylation [134]

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In preclinical studies, 7-HMG demonstrates substantially higher MOR affinity and analgesic potency than MG, with potency approximately 10-fold greater than morphine (Matsumoto et al., 2004