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The elevated phosphorylation levels of key mediators involved in cGAS-STING-dependent innate immune signaling pathway in response to DSF/Cu, including p-STING, p-TBK1, p-IRF3, and p-STAT1, were largely reverted to the levels comparable to the control group upon NAC treatment when stimulated either by ISD or diABZI (Fig

However, as time progressed (6 h), 80%90% of the cancer cells showed metallacycle accumulation implying that the NPs effectively delivered and released the metallacycles to the tumor cells